Bio Hydrogen production breakthrough - Understanding the power of enzymes

December 11 2008 / by Garry Golden
Category: Energy   Year: 2018   Rating: 2

Hydrogenase

 - Editor's Note -
We cannot ignore, or dismiss hydrogen energy storage

Let's put Hydrogen (e.g. energy storage for electricity) into perspective.  Hydrogen was all the hype in the late 90s as Techies rallied behind Ballard Fuel Cell stocks, and buying into the 'hype'.  Then as hydrogen startups failed to live up to short term expectations, many of those same people started slamming hydrogen as a waste of time and resources.  Too 'inefficient and wasteful - and hard to store.'  Early believers had wanted startups to change the world, but really they needed to pay attention to science. Researchers were waving their hands- 'we're not ready yet!'

The hydrogen skeptics' new strategy?
Replace the hype of hydrogen, with hype of lithium ion batteries and capacitors. That's the 'new answer'.  Meanwhile hydrogen researchers continue to evolve systems for low cost, high efficiency production, and solid-state storage. 

My forecast?  Batteries will disappoints us, hydrogen will surprise us.

What happened?
Nanowerk is reporting that researchers at the University of Oxford have advanced a technique that taps the of biology.  Enzymes known as hydrogenase can be used as a cheap, clean and efficient way of producing hydrogen from water using sunlight (artificial photosynthesis).

Hydrogenases are biocatalysts that produce or oxidize hydrogen using clusters of iron ([FeFe]) or nickel and iron ([NiFe]) to facilitate reactions.  Enyzmes transport electrons and positively charged molecules through complex chains that are largely unknown to scientists.  Now we are trying to overcome challenges of tapping the power of hydrogenase (H2 enyzmes) like keeping oxygen from stopping or slowing down reactions. 

Nanowerk reports that Armstrong's group has 'demonstrated a rational photochemical hydrogen cell that produces hydrogen under visible light irradiation without resort to rigorous anaerobicity.'

Why is this important to the future of energy? 

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'Super enzymes' could lower cost of biofuel production

October 22 2008 / by Garry Golden
Category: Environment   Year: 2016   Rating: 1

One of the biggest obstacles in using plant-based biomass (e.g. non-food crops/bio waste) to energy is reducing the cost and energy required to break down the strong cell walls. A way to reduce the costs of biofuels and to use waste biomass to energy, is to find enzymes capable of eating through cell walls.

Researchers at the US Agricultural Research Service (ARS) now believe they have found one of these ‘super enzymes’. ARS Bioproduct Chemistry and Engineering Research Unit’s Charles Lee went looking for enzymes inside dank soil beneath 25-foot-high piles of decaying rice straw, and from the murky liquid from dairy-waste lagoons! (This is where super enzymes hang out to avoid media attention…)

Low temperature = Low cost
Lee’s team then sorted the microbe genes to find the blueprint for super enzymes. From the dairy lagoon sample, the team found a microbe with a gene that they’ve named xyn8. Xylanase is an enzyme that specializes in breaking down xylan, a troublesome component of the hemicellulose in plant cell walls.

Xylanase works well in temperatures regarded as “cold” in the biofuels business. The research group believes that this ‘cold-loving’ enzyme could sidestep the need for the costly heating typically needed at today’s biorefineries.

Read more about the research in the October 2008 issue of Agricultural Research magazine.

Material sourced from press release

Image credit – Peggy Greb, ARS

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